Analytical resolution of a cyclic two‐way chromatographic binary system
Identifieur interne : 001750 ( Main/Exploration ); précédent : 001749; suivant : 001751Analytical resolution of a cyclic two‐way chromatographic binary system
Auteurs : C. Castel [France] ; M. Sardin [France] ; M. O. Simonnot [France]Source :
- AIChE Journal [ 0001-1541 ] ; 2002-02.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
- Aiche, Aiche journal, Analytical solution, Analytical solutions, Anionic resin, Asymptotic, Asymptotic concentration profiles, Asymptotic profile, Asymptotic profiles, Binary mixture, Binary system, Castel, Chem, Chloride, Chloride composition, Chloride profile, Chlorides, Composition velocity discontinuity, Concentration distribution, Concentration profile, Concentration profiles, Critical ratio, Cyclic, Cyclic method, Dharmashankar subramanian, Discontinuity point, Discrete function, Discrete values, Elution, Elution solution, Elution solutions, Elution step, Elution steps, Equilibrium theory, February, Feed solution, Feed step, First elution step, Flow reversal, Fluoride ions, Full line, Hydrogen carbonate, Hydrogencarbonates, Inorganic anion, Ion exchange chromatography, Iterative calculation, Liquid phase, Local equilibrium, Local equilibrium theory, Mass balance, Multicomponent, Multicomponent chromatography, Nlimit, Normality, Numerical series, Numerical simulation, Periodic state, Pressure swing adsorption, Propagation velocity, Saturation step, Scomposition velocity, Selective removal, Sionic fraction, Slongitudinal position, Solid phase, Steady state, Theoretical limit, Theoretical study, Thousandth cycle, Tondeur, Total normality.
- Teeft :
- Aiche, Aiche journal, Analytical solution, Analytical solutions, Asymptotic, Asymptotic concentration profiles, Asymptotic profile, Asymptotic profiles, Binary system, Castel, Chem, Chloride, Chloride composition, Chloride profile, Composition velocity discontinuity, Concentration profile, Concentration profiles, Critical ratio, Cyclic, Dharmashankar subramanian, Discontinuity point, Discrete function, Discrete values, Elution, Elution solution, Elution solutions, Elution step, Elution steps, Equilibrium theory, February, Feed solution, Feed step, First elution step, Flow reversal, Fluoride ions, Full line, Hydrogen carbonate, Iterative calculation, Liquid phase, Local equilibrium theory, Mass balance, Multicomponent, Multicomponent chromatography, Nlimit, Normality, Numerical series, Periodic state, Pressure swing adsorption, Propagation velocity, Saturation step, Scomposition velocity, Selective removal, Sionic fraction, Slongitudinal position, Solid phase, Steady state, Theoretical limit, Thousandth cycle, Tondeur, Total normality.
Abstract
The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.
Url:
DOI: 10.1002/aic.690480208
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000253
- to stream Istex, to step Curation: 000253
- to stream Istex, to step Checkpoint: 000479
- to stream Main, to step Merge: 001A15
- to stream PascalFrancis, to step Corpus: 000891
- to stream PascalFrancis, to step Curation: 000220
- to stream PascalFrancis, to step Checkpoint: 000804
- to stream Main, to step Merge: 001A83
- to stream Main, to step Curation: 001750
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Analytical resolution of a cyclic two‐way chromatographic binary system</title><author><name sortKey="Castel, C" sort="Castel, C" uniqKey="Castel C" first="C." last="Castel">C. Castel</name></author><author><name sortKey="Sardin, M" sort="Sardin, M" uniqKey="Sardin M" first="M." last="Sardin">M. Sardin</name></author><author><name sortKey="Simonnot, M O" sort="Simonnot, M O" uniqKey="Simonnot M" first="M. O." last="Simonnot">M. O. Simonnot</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:6126A07AC7EC6AAA24F1528F5F63A07350DFADF3</idno><date when="2002" year="2002">2002</date><idno type="doi">10.1002/aic.690480208</idno><idno type="url">https://api.istex.fr/document/6126A07AC7EC6AAA24F1528F5F63A07350DFADF3/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000253</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000253</idno><idno type="wicri:Area/Istex/Curation">000253</idno><idno type="wicri:Area/Istex/Checkpoint">000479</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000479</idno><idno type="wicri:doubleKey">0001-1541:2002:Castel C:analytical:resolution:of</idno><idno type="wicri:Area/Main/Merge">001A15</idno><idno type="wicri:source">INIST</idno><idno type="RBID">Pascal:02-0221531</idno><idno type="wicri:Area/PascalFrancis/Corpus">000891</idno><idno type="wicri:Area/PascalFrancis/Curation">000220</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000804</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000804</idno><idno type="wicri:doubleKey">0001-1541:2002:Castel C:analytical:resolution:of</idno><idno type="wicri:Area/Main/Merge">001A83</idno><idno type="wicri:Area/Main/Curation">001750</idno><idno type="wicri:Area/Main/Exploration">001750</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Analytical resolution of a cyclic two‐way chromatographic binary system</title><author><name sortKey="Castel, C" sort="Castel, C" uniqKey="Castel C" first="C." last="Castel">C. Castel</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>LSGC‐CNRS‐INPL, F‐54001 Nancy</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Correspondence address: LSGC‐CNRS‐INPL, F‐54001 Nancy</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author><author><name sortKey="Sardin, M" sort="Sardin, M" uniqKey="Sardin M" first="M." last="Sardin">M. Sardin</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>LSGC‐CNRS‐INPL, F‐54001 Nancy</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author><author><name sortKey="Simonnot, M O" sort="Simonnot, M O" uniqKey="Simonnot M" first="M. O." last="Simonnot">M. O. Simonnot</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>LSGC and EEIGM, F‐54000 Nancy</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">AIChE Journal</title><title level="j" type="alt">AICHE JOURNAL</title><idno type="ISSN">0001-1541</idno><idno type="eISSN">1547-5905</idno><imprint><biblScope unit="vol">48</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="245">245</biblScope><biblScope unit="page" to="251">251</biblScope><biblScope unit="page-count">7</biblScope><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>Hoboken</pubPlace><date type="published" when="2002-02">2002-02</date></imprint><idno type="ISSN">0001-1541</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0001-1541</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aiche</term><term>Aiche journal</term><term>Analytical solution</term><term>Analytical solutions</term><term>Anionic resin</term><term>Asymptotic</term><term>Asymptotic concentration profiles</term><term>Asymptotic profile</term><term>Asymptotic profiles</term><term>Binary mixture</term><term>Binary system</term><term>Castel</term><term>Chem</term><term>Chloride</term><term>Chloride composition</term><term>Chloride profile</term><term>Chlorides</term><term>Composition velocity discontinuity</term><term>Concentration distribution</term><term>Concentration profile</term><term>Concentration profiles</term><term>Critical ratio</term><term>Cyclic</term><term>Cyclic method</term><term>Dharmashankar subramanian</term><term>Discontinuity point</term><term>Discrete function</term><term>Discrete values</term><term>Elution</term><term>Elution solution</term><term>Elution solutions</term><term>Elution step</term><term>Elution steps</term><term>Equilibrium theory</term><term>February</term><term>Feed solution</term><term>Feed step</term><term>First elution step</term><term>Flow reversal</term><term>Fluoride ions</term><term>Full line</term><term>Hydrogen carbonate</term><term>Hydrogencarbonates</term><term>Inorganic anion</term><term>Ion exchange chromatography</term><term>Iterative calculation</term><term>Liquid phase</term><term>Local equilibrium</term><term>Local equilibrium theory</term><term>Mass balance</term><term>Multicomponent</term><term>Multicomponent chromatography</term><term>Nlimit</term><term>Normality</term><term>Numerical series</term><term>Numerical simulation</term><term>Periodic state</term><term>Pressure swing adsorption</term><term>Propagation velocity</term><term>Saturation step</term><term>Scomposition velocity</term><term>Selective removal</term><term>Sionic fraction</term><term>Slongitudinal position</term><term>Solid phase</term><term>Steady state</term><term>Theoretical limit</term><term>Theoretical study</term><term>Thousandth cycle</term><term>Tondeur</term><term>Total normality</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Anion minéral</term><term>Bilan masse</term><term>Chlorure</term><term>Chromatographie échange ion</term><term>Distribution concentration</term><term>Elution</term><term>Equilibre local</term><term>Etude théorique</term><term>Hydrogénocarbonate</term><term>Mélange binaire</term><term>Méthode cyclique</term><term>Résine échangeuse anion</term><term>Simulation numérique</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Aiche</term><term>Aiche journal</term><term>Analytical solution</term><term>Analytical solutions</term><term>Asymptotic</term><term>Asymptotic concentration profiles</term><term>Asymptotic profile</term><term>Asymptotic profiles</term><term>Binary system</term><term>Castel</term><term>Chem</term><term>Chloride</term><term>Chloride composition</term><term>Chloride profile</term><term>Composition velocity discontinuity</term><term>Concentration profile</term><term>Concentration profiles</term><term>Critical ratio</term><term>Cyclic</term><term>Dharmashankar subramanian</term><term>Discontinuity point</term><term>Discrete function</term><term>Discrete values</term><term>Elution</term><term>Elution solution</term><term>Elution solutions</term><term>Elution step</term><term>Elution steps</term><term>Equilibrium theory</term><term>February</term><term>Feed solution</term><term>Feed step</term><term>First elution step</term><term>Flow reversal</term><term>Fluoride ions</term><term>Full line</term><term>Hydrogen carbonate</term><term>Iterative calculation</term><term>Liquid phase</term><term>Local equilibrium theory</term><term>Mass balance</term><term>Multicomponent</term><term>Multicomponent chromatography</term><term>Nlimit</term><term>Normality</term><term>Numerical series</term><term>Periodic state</term><term>Pressure swing adsorption</term><term>Propagation velocity</term><term>Saturation step</term><term>Scomposition velocity</term><term>Selective removal</term><term>Sionic fraction</term><term>Slongitudinal position</term><term>Solid phase</term><term>Steady state</term><term>Theoretical limit</term><term>Thousandth cycle</term><term>Tondeur</term><term>Total normality</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The focus is on analytical resolution of the mass‐balance relation in the case of a binary ion‐exchange system containing chloride and hydrocarbonate anions involved in a two‐way chromatographic cyclic process under critical operating conditions, that is, feed and elution solutions with the same total normality and percolation volumes. Local equilibrium theory is used to demonstrate the convergence of the system toward a periodic state and to calculate iteratively the instantaneous and asymptotic concentration profiles inside the separation column. One of the main results is that the calculated chloride composition on the inlet side of the column after the elution step is equal to the chloride composition in the feed solution.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Nancy</li></settlement></list><tree><country name="France"><region name="Grand Est"><name sortKey="Castel, C" sort="Castel, C" uniqKey="Castel C" first="C." last="Castel">C. Castel</name></region><name sortKey="Castel, C" sort="Castel, C" uniqKey="Castel C" first="C." last="Castel">C. Castel</name><name sortKey="Sardin, M" sort="Sardin, M" uniqKey="Sardin M" first="M." last="Sardin">M. Sardin</name><name sortKey="Simonnot, M O" sort="Simonnot, M O" uniqKey="Simonnot M" first="M. O." last="Simonnot">M. O. Simonnot</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001750 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001750 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Lorraine
|area= LrgpV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:6126A07AC7EC6AAA24F1528F5F63A07350DFADF3
|texte= Analytical resolution of a cyclic two‐way chromatographic binary system
}}
| This area was generated with Dilib version V0.6.32. |  |